Characterization of carbon nanotubes by Raman spectroscopy

نویسندگان

  • S. COSTA
  • E. BOROWIAK-PALEN
  • M. KRUSZYŃSKA
  • A. BACHMATIUK
  • R. J. KALEŃCZUK
چکیده

Application of Raman spectroscopy to analyse carbon nanotubes has been presented. Having a mixture of various carbon nanotube samples, one can easily distinguish, in a quick experiment, presence of singlewalled, doublewalled and multiwalled carbon nanotubes (SWCNT, DWCNT, MWCNT, respectively). The so-called G-line is a characteristic feature of the graphitic layers and corresponds to the tangential vibration of carbon atoms. Another characteristic mode is a typical sign of defective graphitic structures (D-line). A comparison of the intensity ratios of these two peaks gives a measure of the quality of the bulk samples. In addition, there is a third mode, named the radial breathing mode (RBM) which is very sensitive to the diameter of SWCNT and DWCNT. Additional option is application of Raman microscopy for mapping analysis and depth profiling to view the changes of intensity in various directions in the sample.

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تاریخ انتشار 2008